منابع مشابه
Tetrapyrazineplatinum(II) bis(tetrafluoroborate) acetonitrile hemisolvate
The improved synthesis and characterization of tetra-pyrazine-platinum(II) bis-(tetra-fluoro-borate) acetonitrile hemisolvate, [Pt(C(4)H(4)N(2))(4)](BF(4))(2)·0.5CH(3)CN, is reported. The unit cell contains a half equivalent of an acetonitrile solvent mol-ecule per tetra-pyrazine-platinum(II) ion. The coordination geometry of the Pt(II) ion is almost square-planar, with the Pt atom residing on ...
متن کاملtrans-Bis(acetonitrile-κN)tetraaquacobalt(II) tetrachloridocobaltate(II)
In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa-hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra-hedrally coordinated in the anion. An extensive network of O-H(water)⋯Cl hydrogen bonds between cations and anions connects the ions into a three-dimensional network. The Co-Cl distances correlate with the number of hydrogen ...
متن کاملBis(acetonitrile-κN)dichlorido(η4-cycloocta-1,5-diene)ruthenium(II) acetonitrile monosolvate
In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol-ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be o...
متن کاملcis-cis-trans-Bis(acetonitrile-κN)dichloridobis(triphenylphosphine-κP)ruthenium(II) acetonitrile disolvate
The title compound, [RuCl(2)(C(2)H(3)N)(2)(C(18)H(15)P)(2)]·2C(2)H(3)N, was obtained upon stirring an acetonitrile/ethanol solution of [RuCl(2)(PPh(3))(3)]. In the crystal structure, each Ru(II) ion is coordinated by two Cl [Ru-Cl = 2.4308 (7) and 2.4139 (7) Å], two N [Ru-N = 2.016 (2) and 2.003 (2) Å], and two P [Ru-P = 2.3688 (7) and 2.3887 (7) Å] atoms in a distorted octa-hedral geometry. Pa...
متن کاملRedetermination of (acetonitrile-κN)dicarbonyl(η5-cyclopentadienyl)iron(II) tetrafluoridoborate
The crystal structure of the title compound, [Fe(C(5)H(5))(CH(3)CN)(CO)(2)]BF(4), of which only the coordinates of the non-H atoms of the cation have previously been reported [Fadel et al. (1979 ▶). Z. Anorg. Allg. Chem.453, 98-106] has been redetermined. The Fe(II) atom in the complex cation is coordinated by a cyclo-penta-dienyl ring, two carbonyl ligands and an acetonitrile mol-ecule display...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1968
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.26.1107